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The radiolysis of mixtures of carbon monoxide and hydrogen

โœ Scribed by W. H. Beattie

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
531 KB
Volume
5
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

The self-radiolysis of mixtures of CO and tritium (3H2) has been studied at pressures of 0.25 to 1 .O atmospheres, temperatures of -198" to 4-lOO"C, and in the presence of added HzO or COZ. The products of decomposition are COZ, 3H20, C3H4, G3H4, and a white polymer believed to be polyformaldehyde. Initial rates and G values were measured and compared with rates of ion pair formation. The rates of formation of both C o t and C3H4 are independent of temperature and proportional to the energy absorbed in the aHz.

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