The pulse radiolysis of carbon monoxide
โ Scribed by C. Willis; C. Devillers
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 263 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Carbon monoxide has been irradiated with intense pulses of 1 MeV electrons and two transient absorption spectra have been observed. One of these consisted of a series of bands extending from 5000 -8500 b and the second a single line at 2479 A. The species giving rise to the band system is probably C20@) and that to the altigle line ~(1s). It is proposed that carbon atoms are not the exclusive precursors of C20(=) in the system and a reaction involving electronically excited carbon mawxide is ucccrring. co* +co -* Guest Scientist, Division of Pure Physics National Research Council, Ottawa, 1967-68. ** and other references contained in these two publications. *** Manufactured by the Field Emission Corporation,
๐ SIMILAR VOLUMES
The self-radiolysis of mixtures of CO and tritium (3H2) has been studied at pressures of 0.25 to 1 .O atmospheres, temperatures of -198" to 4-lOO"C, and in the presence of added HzO or COZ. The products of decomposition are COZ, 3H20, C3H4, G3H4, and a white polymer believed to be polyformaldehyde.