𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rotational polarization in the chemiluminescent reaction Xe(3P0,2) + Br2 → XeBr* + Br

✍ Scribed by C.T. Rettner; J.P. Simons

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
436 KB
Volume
59
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

A rotor accelerated croCkbeam system has been used to record the ffuorescence spectnzm of XeBr*, produced in the chemiluminescent reaction of Xe(3Pe,2) with Br+, and to monitor for the fmt time, its polarization as a function of reagent ener_q in the range. thermal G Et < 1.25 eV. The results establish (i) that the "primary** and "secondary" bands in the fluorescence speckurn are each associated with parallel polarization (ie. with AS2 = 0); (iii) that the degree of polarization of U prims" band rapidly increases with the collision ener=T, approaching a limiting vahre appropriate to spectator stripping dynamirr

📜 SIMILAR VOLUMES

A crossed molecular beam study of the ch
A crossed molecular beam study of the chemiluminescent reaction Xe(3P2,0) + BrCN → Xe(1S0) + Br + CN(B2Σ+)
✍ R.J. Hennessy; Yoko Ono; J.P. Simons 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 448 KB

The c~ern~~~r~i~c~ce~t intcr~ction of Xef3i' energies ranging up to 70 kJ mol" z,e) artd BrC'N 1x1s been studicd under crossed-beam conditiorls et collision . The CNfR \* X) horuscencc spectrum, the excitation function for its production and the tluorcscence pnlnrisationor rather its absence \_ IWJC

Rotational alignment in inelastic and re
Rotational alignment in inelastic and reactive scattering: Crossed-beam study of the processes Kr(3P2,O) + Br2→ Kr(1So) + Br2* and KrBr(B) + Br
✍ R.J. Hennessy; J.P. Simons 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 342 KB

The reactwe and mclastlc scattcrmg of Kr(3P2 o) and Brz has been studwd over the colhs~on cnergq range 6-70 kJ mol-\* usmg a rotor-accelerated molecular beam &tern hledsuremcnts of fluorescence polarization m the clcctronwzally excltcd products of each channel (KrBr(B) and Brz) estabhsh thclr rotati

Chemiluminescence of CF3 in the visible
Chemiluminescence of CF3 in the visible region from the crossed beam reaction of Ar(3P2,0) with CF3H
✍ H. Ohoyama; T. Kasai; K. Ohashi; Y. Hirata; K. Kuwata 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 354 KB

A metastabie Ar beam was produced by electron impact with glow discharge. The A@P& beam intensity was estimated to be z I x 1 014 atoms sr-' s-'. Crossing this beam with a CF,H beam, collision-free emission of CF3 in the visible region was observed. The intensity maximum of the newly observed emiss