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Rotational effects on the S0-T1 oscillator strength of pyrazine

✍ Scribed by A. Penner; Y. Oreg; E. Villa; E.C. Lim; A. Amirav

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 523 KB
Volume: 150
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)80035-6

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✦ Synopsis

The rotationally resolved S,+T, transition of jet-cooled pyrazine has been studied using phosphorescence excitation and multiphoton ionization spectroscopy. A computer simulation that divides the relative transition intensity by 2J+ 1 successfully reproduces the experimental spectra. The results are interpreted in terms of a possible spin-rotational-orientational selectivity in the singlet-triplet coupling that governs the transition oscillator strength.

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