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Effects of limited CI on T1 → S0 oscillator strength and phosphorescence lifetime of pyrazine

✍ Scribed by William Roy Hall

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
318 KB
Volume
37
Category
Article
ISSN
0009-2614

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✦ Synopsis

Using modified CNDO/S/CI wavefunctions, the effects of 10, 20, 30 and no CI on the oscillator strength of the TI -c So transition and phosphorescence Lifetim= of pyrazine was investigated. From these caiculations, it was determined that although the individuaI numbers vzried, the order of magnitude remained fairly constant, appro.ximately IO-* s. The closest results to the experimental values for oscillator strength and phosphorescence Iifetime wins obtained with 20 an? 30 CI

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