✦ LIBER ✦

The large effects of electron correlation on the multiplet generalized oscillator strengths of non-closed shell systems: Be 1s22s21S → 1s22s2p 1P0 and B 1s22s22p 2p0 → 1s22s2p22D

✍ Scribed by Oktay Sinanoǧlu; Stephen L. Davis

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 679 KB
Volume: 32
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)85212-2

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✦ Synopsis

Correlation effects are shown to change generalized oscillator strengths and inelr&c form factors by large factors a5 large as 10, from the Hartree-Fock values. The effects are fully included in the charge wavefunctions of the non-closed shell mny-electron theory by Sirmna~u. We calculate ihe charge wvavefunctions and obtzin from them the gcner&zed OScfitor strength Iron(q) VPISUS In q2 and the integrated cross section Q,(E) versus In E, far Be1 2s2 tS --c 2~2~ 'PO and BI ZP zp .= PO + 2s2pz = D cases, exemplifying the method. Electron impact spectroscopy measures the apparent generalized oscillator strength; Fn, (q), between initial p,(i) =jexp(b*r)Pen(r)dr ,iJolurik'32; number 3. ,-CHEMICAL PHYSICS LETTERS ',

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