✦ LIBER ✦

Rotational effects on fluorescence quantum yields of pyrazine and pyrimidine in the vapor phase

✍ Scribed by Hiroaki Baba; Masahisa Fujita; Katsuo Uchida

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 333 KB
Volume: 73
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)80687-7

No coin nor oath required. For personal study only.

✦ Synopsis

Fluorescence-excitation and quantum-yield spectra were measured along the rotational contours of the O-O and lOa: bands of pyrazme and the O-O band of pyrimidme in the vapor phase at low pressure. A marked variation in quantum yield was observed. The yield spectra for the O-O bands exhiiit a very sharp peak near the band origin_ It is sumsted that the S-T coupling is enhanced with increasing rotation.

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