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Rotation-vibration spectrum of CH3F in the range 2000–2100 cm−1

✍ Scribed by Michel Betrencourt

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
735 KB
Volume
47
Category
Article
ISSN
0022-2852

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Millimeter-wave and submillimeter-wave spectra of the rotational transitions in the \(v_{2}=1\) and \(v_{5}=1\) vibrational states of \({ }^{13} \mathrm{CH}_{3} \mathrm{~F}\) were measured up to \(462 \mathrm{GHz}\). Far-infrared spectra of these transitions were measured in the region \(30-65 \math

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A representation of the effective rotational Hamiltonian in the form of optimum versions of a rational series of the perturbation theory is suggested for nonisolated molecular states. This representation is used to analyze the most complete set of precise transition frequencies in the rotational spe