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Infrared rotation and vibration—rotation bands of endohedral fullerene complexes. Absorption spectrum of Li+ @C60 in the range 1–1000 cm−1

✍ Scribed by C.G. Joslin; J. Yang; C.G. Gray; S. Goldman; J.D. Poll


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
618 KB
Volume
208
Category
Article
ISSN
0009-2614

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📜 SIMILAR VOLUMES


Infrared rotation and vibration—rotation
✍ C.G. Joslin; J. Yang; C.G. Gray; S. Goldman; J.D. Poll 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 602 KB

We compute the far-infrared absorption spectrum ofthe endohedral metallofullerene K+@&. This arises from the vibrational and rotational motion of the potassium ion about its equilibrium position at the center of the buckyball cage. The spectrum is quite unusual. Although the permanent dipole moment

Infrared rotation and vibration—rotation
✍ C.G. Joslin; C.G. Gray; J.D. Goddard; S. Goldman; J. Yang; J.D. Poll 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 439 KB

The endohedral fullerene He@&, is potentially responsible for unidentified infrared bands in molecular clouds. In this species overlap effects induce a small dipole moment. We have computed the induced dipole and endohedral potential using self-consistent field Hartree-Fock theory. Using these resul

Infrared rotation and vibration—rotation
✍ C.G. Joslin; C.G. Gray; S. Goldman 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 593 KB

We calculate the far-infrared absorption spectrum associated with the vibrational and rotational motion of a He atom enclosed in a nanotube of diameter 0.7 nm, formed by rolling up a single sheet of graphite and capping each end with one half of a CsO molecule. The endohedral potential and dipole mo