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Role of β-H Elimination in Rhodium-Mediated Carbene Insertion Polymerization

✍ Scribed by Finger, Markus; Reek, Joost N. H.; de Bruin, Bas


Book ID
125922829
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
1017 KB
Volume
30
Category
Article
ISSN
0276-7333

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Diastereoselection in rhodium-mediated i
✍ Douglass F. Taber; Robert E. Ruckle Jr. 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 184 KB

Transition state analysis suggests that substantial 1,2 asymmetric induction could be observed in the course of rhodium-mediated intramolecular C-H insertion. This analysis successfully predicts predominant formation of the trans 3,4-dialkyl cyclopentane when an a-diazo P-ketoester having a 6-pheny