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Diastereoselection in rhodium-mediated intramolecular C-H insertion: preparation of a trans-3,4 dialkyl cyclopentane

โœ Scribed by Douglass F. Taber; Robert E. Ruckle Jr.

Book ID
104228769
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
184 KB
Volume
26
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Transition state analysis suggests that substantial 1,2 asymmetric induction could be observed in the course of rhodium-mediated intramolecular C-H insertion.

This analysis successfully predicts predominant formation of the trans 3,4-dialkyl cyclopentane when an a-diazo P-ketoester having a 6-phenyl -substituent is cyclized. 1984, 2, 508. b) Jones, W. D.; Feher, F.

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