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Rhodium(II)-carbenoid C–H insertion reactions in the synthesis of β-oxospirane systems

✍ Scribed by Aburel, Pompiliu S.; Undheim, Kjell

Book ID
118267374
Publisher
Royal Society of Chemistry
Year
2000
Weight
162 KB
Volume
12
Category
Article
ISSN
1472-7781

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📜 SIMILAR VOLUMES

ChemInform Abstract: Rhodium(II)-Carbeno
ChemInform Abstract: Rhodium(II)-Carbenoid C—H Insertion Reactions in the Synthesis of α,β′-Dioxospirane Systems.
✍ Pompiliu S. Aburel; Christian Roemming; Kjell Undheim 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

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Synthesis of spirosystems by rhodium(II)
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✍ Pompiliu S. Aburel; Kjell Undheim 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 137 KB

A simple one-pot procedure is described for the preparation of spiro [4,4]nonane-2,7-dione derivatives from open chain bis(oc-diazoketones). The reactions proceed by an intramolecular Rh(II)carbenoid insertion into a methylene C-H bond yielding a cyclopentane which subsequently undergoes C-H methine

ChemInform Abstract: Synthesis of Spiros
ChemInform Abstract: Synthesis of Spirosystems by Rhodium(II)-Carbenoid C—H Insertion Reactions.
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