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Role of Water in the Structure of Psilomelane, (Ba,H2O)2Mn5O10

โœ Scribed by WADSLEY, A. D.


Book ID
109572027
Publisher
Nature Publishing Group
Year
1952
Tongue
English
Weight
203 KB
Volume
170
Category
Article
ISSN
0028-0836

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Hydrothermal Synthesis and Crystal Struc
โœ Yasushi Kanke; Yoshio Oka; Takeshi Yao ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 365 KB

A new V IV /V V mixed-valence polyoxovanadate compound Ba 6 [V 10 O 30 (H 2 O)] ' 2.5H 2 O has been hydrothermally synthesized in an NaVO 3 +BaI 2 +(CH 3 ) 4 NI aqueous solution system. The compound crystallizes cubic, Im3 , a โ€ซุโ€ฌ 16.8323(2) A s , and Z โ€ซุโ€ฌ 6. The structural analysis gave wR2 โ€ซุโ€ฌ 0.