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The crystal structure of psilomelane, (Ba, H2O)2Mn5O10

โœ Scribed by Wadsley, A. D.

Book ID
114516133
Publisher
International Union of Crystallography
Year
1953
Tongue
English
Weight
700 KB
Volume
6
Category
Article
ISSN
0365-110X

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Hydrothermal Synthesis and Crystal Struc
Hydrothermal Synthesis and Crystal Structure of Ba6[V10O30(H2O)]ยท2.5H2O with an Unusual Arrangement of VIVโ€“O Polyhedra
โœ Yasushi Kanke; Yoshio Oka; Takeshi Yao ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 365 KB

A new V IV /V V mixed-valence polyoxovanadate compound Ba 6 [V 10 O 30 (H 2 O)] ' 2.5H 2 O has been hydrothermally synthesized in an NaVO 3 +BaI 2 +(CH 3 ) 4 NI aqueous solution system. The compound crystallizes cubic, Im3 , a โ€ซุโ€ฌ 16.8323(2) A s , and Z โ€ซุโ€ฌ 6. The structural analysis gave wR2 โ€ซุโ€ฌ 0.