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Role of the ligand in the palladium-catalyzed C-2 and C-3 arylation of the indole magnesium salt

โœ Scribed by Nikulin, M. V.; Lebedev, A. Yu.; Voskoboinikov, A. Z.; Beletskaya, I. P.

Book ID
110160127
Publisher
Springer
Year
2008
Tongue
English
Weight
168 KB
Volume
423
Category
Article
ISSN
0012-5008

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โœ Lane, Benjamin S.; Brown, Meghann A.; Sames, Dalibor ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 256 KB

We have recently developed palladium-catalyzed methods for direct arylation of indoles (and other azoles) wherein high C-2 selectivity was observed for both free (NH)-indole and (NR)-indole. To provide a rationale for the observed selectivity ("nonelectrophilic" regioselectivity), mechanistic studie