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ChemInform Abstract: Recent Advances in the C2 and C3 Regioselective Direct Arylation of Indoles

✍ Scribed by Nathalie Lebrasseur; Igor Larrosa

Book ID
112047894
Publisher
John Wiley and Sons
Year
2012
Weight
18 KB
Volume
43
Category
Article
ISSN
0931-7597

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We have recently developed palladium-catalyzed methods for direct arylation of indoles (and other azoles) wherein high C-2 selectivity was observed for both free (NH)-indole and (NR)-indole. To provide a rationale for the observed selectivity ("nonelectrophilic" regioselectivity), mechanistic studie