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Role of density fluctuations in bimolecular reaction kinetics

โœ Scribed by A.A. Ovchinnikov; Ya.B. Zeldovich

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
355 KB
Volume
28
Category
Article
ISSN
0301-0104

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๐Ÿ“œ SIMILAR VOLUMES

Effect of reagent density fluctuations o
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The pccuhwnics oithe kineucsoT3 blmolccular re3ctlon A + B -C cwwd by non-Poluon fluctuations of rcgunt dcn-511~s spon~ancously produced durmg a dnIusioncon~roUcd rcxtlon xc mdyscd. The 3symptollc long-time Lmcucs IS predlcted to bc n c: I-"' (for qua reqent concentmt~ons) contrzuy LO :he or&nary lw

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S~~~YIUI~ from the generalized theory of blmolwlar diffusion-controlled reactiorus betwatn reagents in soli& and liquids, we have performed calculations of Lhe A+B \* AB (F'renkel defecL anmhilalion) and A+A + B (exciton annihdation) reaction kinetics over a wide time interval and for high initial c