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Ring opening and ring closure of vinylcyclopropanes on Rh and application to unstrained CC bond cleavage

✍ Scribed by Chul-Ho Jun; Jung-Bu Kang; Yeong-Gweon Lim

Book ID
103398684
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
215 KB
Volume
36
Category
Article
ISSN
0040-4039

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Alkyne and ketone induced novel cleavage
Alkyne and ketone induced novel cleavage of a CC bond and a CSi bond in zirconacyclobutene–silacyclobutene fused ring compounds
✍ Tao Yu; Liang Deng; Changjia Zhao; Zhiping Li; Zhenfeng Xi 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 244 KB

Novel cleavage patterns of C C bonds and C Si bonds were achieved via alkyne-or ketone-induced reactions of zirconacyclobutene-silacyclobutene fused ring compounds; thermodynamically favored six-membered zirconacyclohexadiene derivatives were formed in excellent yields from the four-membered zircona