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Alkyne and ketone induced novel cleavage of a CC bond and a CSi bond in zirconacyclobutene–silacyclobutene fused ring compounds

✍ Scribed by Tao Yu; Liang Deng; Changjia Zhao; Zhiping Li; Zhenfeng Xi

Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 244 KB
Volume: 44
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)02673-4

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✦ Synopsis

Novel cleavage patterns of C C bonds and C Si bonds were achieved via alkyne-or ketone-induced reactions of zirconacyclobutene-silacyclobutene fused ring compounds; thermodynamically favored six-membered zirconacyclohexadiene derivatives were formed in excellent yields from the four-membered zirconacyclobutenes via this unprecedented alkyne-induced

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