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Reactions of (Me2C)(Me2Si)[(η5-C5H3)­Mo(CO)3]2 with Phosphanylalkynes: Rearrangement of Phosphanylalkynes into Phosphido-Substituted Vinylidenyl Ligands by Cleavage of the P–C(alkyne) Bond and Formation of a P–C(alkene) Bond

✍ Scribed by Bin Li; Shansheng Xu; Haibin Song; Baiquan Wang

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
436 KB
Volume
2008
Category
Article
ISSN
1434-1948

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The yellow-orange boratabenzene complex Cb\*Co(3,5-Me 2 C 5 H 3 BNMe 2 ) (1) (Cb\* = C 4 Me 4 ) was readily obtained from [Cb\*Co(NCMe) 3 ]PF 6 and Li(TMEDA)(3,5-Me 2 C 5 H 3 BNMe 2 ). Methanolysis of 1 afforded Cb\*Co(3,5-Me 2 C 5 H 3 BOMe) (2). Complex 2 reacted with MeLi and with BCl 3 to give th