Rhodium-catalyzed CC bond formation by ring-opening of alkylidenecyclopropanes and insertion of 3-butenoic acid
✍ Scribed by Gian Paolo Chiusoli; Mirco Costa; Paolo Schianchi; Giuseppe Salerno
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 261 KB
- Volume
- 315
- Category
- Article
- ISSN
- 0022-328X
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The catalytic functionalization of unreactive C À H bonds remains one of the major challenges in chemistry. [1] Metal ± boryl systems have been shown to promote stoichiometric [2] and photocatalytic [3] conversion of alkane and arene CÀH bonds into CÀB(OR) 2 groups by using B 2 pin 2 (pin OC-Me 2 CM