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Ring opening and closing reactions of imidazoles and other 1,3-diazaheterocycles with vinyl chloroformate and phenyl chloroformate

✍ Scribed by R.F. Pratt; K.K. Kraus

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
229 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis

Treatment of imidazole and benzimidazole with vinyl chloroformate or phenyl chloroformate in weakly alkaline aqueous solution leads to their conversion into the corresponding imidazol-Z-ones; in weakly acidic solutions these chloroformates convert adenine into isoguanine, 6methylaminopurine into 1-methylisoguanine and pyrimidine into an acyclic product.

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