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Cycloaddition of Acyclic Nitrones with Phenyl Isocyanate: Synthesis and Ring-Opening Reactions of 1,2,4-Oxadiazolidin-5-ones.

✍ Scribed by Necdet Coskun; Aydin Parlar


Publisher
John Wiley and Sons
Year
2006
Weight
14 KB
Volume
37
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES


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In a continuing study of cycloaddition reactions involving cyclopropane ring-containing systems (1) we have investigated the reactions of vinylcyclopropane and some substituted vinylcyclopropanes with 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) and chlorosulfonylisocyanate (CSI).

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5-Imino-1,2,4-thiadiazolidin-3-ones 1 react with compounds alkylidene-1,2,4-dithiazolidines 12 are formed. The reaction products with enamines undergo hydrolysis and elimination containing electron-rich double bonds such as enamines and ester enolates to afford the 2-iminothiazolidines 3, 4, and 10

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✍ Wróblewski, Andrzej E. 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 511 KB

Addition of dimethyl phosphonate to acetaldol gives a 3 : 7 mixture of diastereomeric dimethyl (1,3-dihydroxybutyl)phosphonates 3 and 4. The relative configurations at C-I and C-3 in these diols were established by the 13C NMR data of their 0-benzylidene derivatives. Axial preference-for the dimetho