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The reaction of chloroform and sodium methoxide with cyclooctene, 1,5-cyclooctadiene and 1,3,6-cyclooctatriene

✍ Scribed by David I. Schuster; Fui-Tseng Lee

Publisher: Elsevier Science
Year: 1965
Tongue: French
Weight: 333 KB
Volume: 6
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)99575-9

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✦ Synopsis

It was.recently reported that dichlorocarbene, as generated from chloroform and sodium methexide, adds to an excess of cyclooctene (A), 1,3,6-cyclooctatriene (2), and 1,3,5-cyclooctatriene (J), as well as assorted alkyl, cycloalkyl, aryl and alkoxy derivatives, to give products with the bicyclo[4.2.l]nonane skeleton. 1 Thus, the products from 1 and 2 (or 2) were claimed to be 2 and 5, respectivelyl.

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