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Ring closing metathesis employing organometallic substrates and the templated synthesis of macrocycles

✍ Scribed by Preston A. Chase; Martin Lutz; Anthony L. Spek; Gerard P.M. van Klink; Gerard van Koten

Book ID
108212660
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
753 KB
Volume
254
Category
Article
ISSN
1381-1169

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Synthesis of macrocyclic lactams and lac
Synthesis of macrocyclic lactams and lactones via ring-closing olefin metathesis
✍ William P.D. Goldring; AndrΓ©S. Hodder; Larry Weiler πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 254 KB

## A&Wrack Lactones and lactams 4-6 were synthesized from a series of acyclic dienes 1-3 via ringclosing olefin metathesis, as shown in equation 1. The geometry of the resulting double bond was determined, and the UZratios compared to values from molecular mechanics calculations.