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Rh/Pd Catalysis with Chiral and Achiral Ligands: Domino Synthesis of Aza-Dihydrodibenzoxepines

✍ Scribed by Friedman, Adam A.; Panteleev, Jane; Tsoung, Jennifer; Huynh, Vaizanne; Lautens, Mark


Book ID
120559877
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
771 KB
Volume
52
Category
Article
ISSN
0044-8249

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✍ James M. Longmire; Xumu Zhang πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 204 KB

A general strategy for the synthesis of new chiral phosphine ligands has been discovered. A common feature of these ligands is that they contain rigid aromatic backbones which can be used to restrict conformational flexibility. The bite angle of P-M-P can be changed systematically depending on the