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Regiospecific and stereoselective alkylation of allylic substrates on Pd, Ir, and Rh complexes with chiral phosphite ligands

✍ Scribed by Kabro, A. A.; Lyubimov, S. E.; Ikonnikov, N. S.; Zheglov, S. V.; Maksimova, M. G.; Moiseev, S. K.; Davankov, V. A.; Gavrilov, K. N.; Kalinin, V. N.


Book ID
110160007
Publisher
Springer
Year
2007
Tongue
English
Weight
246 KB
Volume
415
Category
Article
ISSN
0012-5008

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The rhodium(I)-catalyzed enantioselective hydrogenation of E-and Z-configured b-acylamido b-alkylacrylates as well as of isomeric mixtures has been investigated. As ligands 1,2-bisphospholanes like DuPHOS, BPE and Me 4 -BASPHOS have been tested, but also diphosphines forming seven-membered chelates