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Asymmetric synthesis of chiral Roche ester and its derivatives via Rh-catalyzed enantioselective hydrogenation with chiral phosphine-phosphoramidite ligands

✍ Scribed by Min Qiu; Dao-Yong Wang; Xiang-Ping Hu; Jia-Di Huang; Sai-Bo Yu; Jun Deng; Zheng-Chao Duan; Zhuo Zheng

Book ID: 108284424
Publisher: Elsevier Science
Year: 2009
Tongue: English
Weight: 408 KB
Volume: 20
Category: Article
ISSN: 0957-4166
DOI: 10.1016/j.tetasy.2008.12.026

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## Abstract Six chiral monodentate ligands combining a 1,3‐dioxa‐2‐phosphacycloheptadinaphthyl moiety [(__R__)‐ or (__S__)‐binoP] either with a phenylalanine‐ or with an alanine‐derived fragment were synthesised. The new phosphoramidites are all relatively air stable. Related compounds in which the