Rhodium(III) complexes of benzo[h]quinoline and 2-phenylpyridine
✍ Scribed by Matsuo Nonoyama; Kazuo Yamasaki
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 149 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0020-1650
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## Abstract Heating [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(CH~2~CMe~2~Ph)] (1; dtbpy = 4,4′‐di‐__tert__‐butyl‐2,2′‐bipyridyl) in __p__‐xylene at 110 °C resulted in the formation of the 2‐__tert__‐butylphenyl complex [Rh(dtbpy)(κ~2~‐__C,C′__‐CH~2~CMe~2~C~6~H~4~)(C~6~H~4~__t__Bu‐2)] (3). Treat
## Abstract A convenient method is presented for the first time for the direct separation of enantiomers of a tris(2‐phenylpyridine) iridium (III) and an analog substituted with long alkoxy chains on polysaccharide derivative‐based chiral stationary phases by HPLC. Tris(2‐phenylpyridine) iridium (I