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Synthesis, structure, and reactivity of ylide rhodium(I) and rhodium (III) complexes

✍ Scribed by H. Werner; O. Schippel; J. Wolf; M. Schulz

Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 952 KB
Volume: 417
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(91)80169-k

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## Abstract The reaction of [{RhCl(C~8~H~14~)~2~}~2~] (2) with __i__Pr~2~PCH~2~CH~2~C~6~H~5~ (L^1^) led, via the isolated dimer [{RhCl(C~8~H~14~)(L^1^)}~2~] (3), to a mixture of three products 4 a–c, of which the dinuclear complex [{RhCl(L^1^)~2~}~2~] (4 a) was characterized by Xray crystallography