Rhodium(I)-Catalyzed Intramolecular Hydroacylation of 4,6-Dienals: Novel Synthesis of Cycloheptenones.
β Scribed by Yoshihiro Oonishi; Miwako Mori; Yoshihiro Sato
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 35 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Mild intramolecular hydroacylation of Ξ±,Ξ±βdisubstituted 4βalkylidenecyclopropanals, such (I), (VII), and (IX) is described avoiding decarbonylation and affording cycloheptenones (II), (VIII), and (X) in good yields.