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ChemInform Abstract: Facile and Chemoselective Rhodium-Catalyzed Intramolecular Hydroacylation of α,α-Disubstituted 4-Alkylidenecyclopropanals.

✍ Scribed by Damien Crepin; Coralie Tugny; James H. Murray; Christophe Aissa

Publisher: John Wiley and Sons
Year: 2012
Weight: 42 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201207046

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✦ Synopsis

Abstract

Mild intramolecular hydroacylation of α,α‐disubstituted 4‐alkylidenecyclopropanals, such (I), (VII), and (IX) is described avoiding decarbonylation and affording cycloheptenones (II), (VIII), and (X) in good yields.

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