Several rhodium(I) complexes containing chiral phosphine, (+) DIOP, (+> BINAP, (S,S) CHIRAPHOS, and (S)(R) BPPFA, have been found to be effective as catalyst for the asymmetric hydrobomtion of pm&h-al alkenes with catecholborane (1,3,2benzodioxaborole) to give optically active 2-alkyl-1,3,2-benzodio
β¦ LIBER β¦
Rhodium(I)-catalysed hydroboration of 1-halo-1-alkenes
β Scribed by Said Elgendy; Geeta Patel; Vijay V. Kakkar; Goran Claeson; Donovan Green; Emmanuel Skordalakes; Jehan A. Baban; John Deadman
- Book ID
- 103404573
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- French
- Weight
- 112 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Rhodium(i)-catalyzed asymmetric hydrobor
β
Makoto Sato; Norio Miyaura; Akira Suzuki
π
Article
π
1990
π
Elsevier Science
π
French
β 273 KB
Vinylic organoboranes. 12. Synthesis of
β
Brown, Herbert C.; Blue, Clarence D.; Nelson, Donna J.; Bhat, Narayan G.
π
Article
π
1989
π
American Chemical Society
π
English
β 535 KB
Asymmetric Hydroboration of 1,1-Disubsti
β
Stephenβ
P. Thomas; Varinderβ
K. Aggarwal
π
Article
π
2009
π
John Wiley and Sons
π
English
β 262 KB
π 2 views
## Abstract **A breakthrough** in the asymmetric hydroboration of notoriously difficult 1,1βdisubstituted alkenes using a new family of highly effective hydroboration reagents is described (see scheme). The intermediate boranes can be oxidized to alcohols or used in SuzukiβMiyaura crossβcoupling re
One-Pot Rhodium(I)-Catalyzed Hydroborati
β
Philippe Renaud; Cyril Ollivier; Valery Weber
π
Article
π
2003
π
John Wiley and Sons
β 213 KB
One-Pot Rhodium(I)-Catalyzed Hydroborati
β
Renaud, Philippe; Ollivier, Cyril; Weber, ValΓ©ry
π
Article
π
2003
π
American Chemical Society
π
English
β 76 KB
ChemInform Abstract: Asymmetric Hydrobor
β
Stephen P. Thomas; Varinder K. Aggarwal
π
Article
π
2009
π
John Wiley and Sons
β 15 KB
π 2 views