Rhodium(i)-catalyzed asymmetric hydrobor
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Makoto Sato; Norio Miyaura; Akira Suzuki
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Article
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1990
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Elsevier Science
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French
โ 273 KB
Several rhodium(I) complexes containing chiral phosphine, (+) DIOP, (+> BINAP, (S,S) CHIRAPHOS, and (S)(R) BPPFA, have been found to be effective as catalyst for the asymmetric hydrobomtion of pm&h-al alkenes with catecholborane (1,3,2benzodioxaborole) to give optically active 2-alkyl-1,3,2-benzodio