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Rhodium Cluster Complexes Containing Bridging Phenylgermanium Ligands

✍ Scribed by Adams, Richard D.; Smith, Jack L.

Book ID
125928824
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
254 KB
Volume
44
Category
Article
ISSN
0020-1669

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The recently reported complex, [l] [Rh,(CO)2-(/+&O)(@)(DPM),] BPh4, (l), (DPM = bis(diphenylphosphino)methane; Ph = CsHs), is the first structurally characterized example of an "A-frame" complex containing a ligand in the proposed "active site", bridging the two metal atoms. This carbonylbridged ca