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Dimeric rhodium(II) complexes containing bridging mandelate ligands

✍ Scribed by Pruchnik, Florian; James, Brian R.; Kvintovics, Pál

Book ID
120167481
Publisher
NRC Research Press
Year
1986
Tongue
French
Weight
359 KB
Volume
64
Category
Article
ISSN
0008-4042

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✍ Martin Cowie; Stephen K Dwight; Alan R Sanger 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 301 KB

The recently reported complex, [l] [Rh,(CO)2-(/+&O)(@)(DPM),] BPh4, (l), (DPM = bis(diphenylphosphino)methane; Ph = CsHs), is the first structurally characterized example of an "A-frame" complex containing a ligand in the proposed "active site", bridging the two metal atoms. This carbonylbridged ca