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Carbonyl complexes of rhodium (I) with bridge nitrogen-containing ligands

✍ Scribed by G.I. Karyakina; M. L. Khidekel'


Book ID
112434244
Publisher
Springer
Year
1969
Tongue
English
Weight
144 KB
Volume
18
Category
Article
ISSN
1573-9171

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## Rhodium(I) carbonyl complexes, namely [Rh(CO)2C1L ] where L = thiourea (Tu), 1,3-diphenyl-2-thiourea (DTu), dithizone (Dtz), indole (Id), 3-chloropyridine (Clpy), 3hydroxypyridine (HOpy), 3-methylpyridine (Mepy), 2,5dimethylpyridine (Me2py) or 2,5-dichloropyridine (C12py)] were prepared. [Rh(CO

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The recently reported complex, [l] [Rh,(CO)2-(/+&O)(@)(DPM),] BPh4, (l), (DPM = bis(diphenylphosphino)methane; Ph = CsHs), is the first structurally characterized example of an "A-frame" complex containing a ligand in the proposed "active site", bridging the two metal atoms. This carbonylbridged ca