## Rhodium(I) carbonyl complexes, namely [Rh(CO)2C1L ] where L = thiourea (Tu), 1,3-diphenyl-2-thiourea (DTu), dithizone (Dtz), indole (Id), 3-chloropyridine (Clpy), 3hydroxypyridine (HOpy), 3-methylpyridine (Mepy), 2,5dimethylpyridine (Me2py) or 2,5-dichloropyridine (C12py)] were prepared. [Rh(CO
β¦ LIBER β¦
Rhodium(I) carbonyl complexes with heterocyclic and nonheterocyclic nitrogen-donor ligands
β Scribed by Dipak K. Dutta; Mono M. Singh
- Publisher
- Springer
- Year
- 1979
- Tongue
- English
- Weight
- 484 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0340-4285
No coin nor oath required. For personal study only.
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The dimeric rhodium precursor [Rh(CO) 2 Cl] 2 reacts with two molar equivalent of 9,9-dimethyl-4,5bis (diphenylphosphino)xanthene [xantphos] (a), bis(2-diphenylphosphinophenyl)ether [DPEphos] (b) and their corresponding dioxide analogues xantphos dioxide (c), DPEphos dioxide (d) to afford the monoan