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Complexes with heterocyclic nitrogen ligands—III. Cationic rhodium(I) derivatives and applications in catalysis

✍ Scribed by Sergio A. Moya; Ruben Pastene; Renato Sariego; Rebeca Sartori; Pedro Aguirre; Hubert Le Bozec


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
395 KB
Volume
15
Category
Article
ISSN
0277-5387

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The reaction of cationic diolefinic rhodium(I) complexes with 2-(diphenylphosphino)benzaldehyde (pCHO) was studied. [Rh(cod) 2 ]ClO 4 (cod cycloocta-1,5-diene) reacted with pCHO to undergo the oxidative addition of one pCHO with (1,2,3-h)cyclooct-2-en-1-yl (h 3 -C 8 H 13 ) formation, and the coordin