✦ LIBER ✦

Rhodium Chemzymes: Michaelis−Menten Kinetics in Dirhodium(II) Carboxylate-Catalyzed Carbenoid Reactions

✍ Scribed by Pirrung, Michael C.; Liu, Hao; Morehead, Andrew T.

Book ID: 127080648
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 128 KB
Volume: 124
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja011599l

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Diazirines in carbenoid reactions cataly

Diazirines in carbenoid reactions catalyzed by rhodium(II) carboxylates

✍ Michael P. Doyle; Kenneth G. High; Su-Min Oon; Antonio K. Osborn 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 271 KB

Diazo compounds formed by thermal or photolytic rearrangement of 3-alkyl-3-phenyldiazirines in the presence of catalytic amounts of rhodium(ll) perfluorobutyrate are effectively directed to metal carbenoid products with minimal competition from processes which are dominant when the diazo compound is

Highly selective γ-lactone syntheses by

Highly selective γ-lactone syntheses by intramolecular carbenoid carbon-hydrogen insertion in rhodium(II) carboxylate and rhodium(II) carboxamide catalyzed reactions of diazo esters

✍ Michael P. Doyle; Vahid Bagheri; Matthew M. Pearson; John D. Edwards 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 251 KB

Rhodium(k) acetate and rhodium(h) acetamide catalyzed decomposition of diazo esters forms "I-lactones in high yield and with exceptionally high regio-and diastereoselectivity.