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Diazirines in carbenoid reactions catalyzed by rhodium(II) carboxylates

✍ Scribed by Michael P. Doyle; Kenneth G. High; Su-Min Oon; Antonio K. Osborn

Book ID: 104229551
Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 271 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99399-7

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✦ Synopsis

Diazo compounds formed by thermal or photolytic rearrangement of 3-alkyl-3-phenyldiazirines in the presence of catalytic amounts of rhodium(ll) perfluorobutyrate are effectively directed to metal carbenoid products with minimal competition from processes which are dominant when the diazo compound is used directly or when the diazirine is decomposed in the absence of the catalyst.

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