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Highly selective γ-lactone syntheses by intramolecular carbenoid carbon-hydrogen insertion in rhodium(II) carboxylate and rhodium(II) carboxamide catalyzed reactions of diazo esters

✍ Scribed by Michael P. Doyle; Vahid Bagheri; Matthew M. Pearson; John D. Edwards

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 251 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93408-2

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✦ Synopsis

Rhodium(k) acetate and rhodium(h) acetamide catalyzed decomposition of diazo esters forms "I-lactones in high yield and with exceptionally high regio-and diastereoselectivity.

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