𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rhodium-Catalyzed Selective anti -Markovnikov Addition of Carboxylic Acids to Alkynes

✍ Scribed by Lumbroso, Alexandre; Vautravers, Nicolas R.; Breit, Bernhard


Book ID
126298445
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
375 KB
Volume
12
Category
Article
ISSN
1523-7060

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Ruthenium-catalyzed selective anti-Marko
✍ Karen Melis; Pawel Samulkiewicz; Jacek Rynkowski; Francis Verpoort πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 142 KB

Carboxylic acids react with terminal alkynes in the presence of a catalytic amount of RuCl x (p-cymene)(triazol-5-ylidene) to selective generate Z-alk-1-en-1-yl esters. The anti-Markovnikov and trans addition on the terminal alkyne gives access to Z-alkene derivatives of phenylacetylene, t-butylacet