Rhodium-Catalyzed Reaction of N-(2-Pyridinyl)piperazines with CO and Ethylene. A Novel Carbonylation at a C-H Bond in the Piperazine Ring. -The electronic nature of substituents, both on the 4-nitrogen and in the pyridine ring, affects significantly the reactivity of the substrates in the novel tit
✦ LIBER ✦
Rhodium-Catalyzed Reaction of N -(2-Pyridinyl)piperazines with CO and Ethylene. A Novel Carbonylation at a C−H Bond in the Piperazine Ring
✍ Scribed by Ishii, Yutaka; Chatani, Naoto; Kakiuchi, Fumitoshi; Murai, Shinji
- Book ID
- 126989957
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 352 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0276-7333
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The reaction of N-acylpiperazineswith CO (15 arm) and ethylene at 160 'C in the presenceof Rh4(CO),2results in dehydrogenation and carbonylationat a C-H bond. This ceaction representsthe first exampleof carbonylationat a C-H bondpromotedby an oxygenfunctionalgroup.
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