Rhodium-Catalyzed C-H—CO—Olefin Coupling Reactions — A Chelation-Assisted Direct Carbonylation at the ortho C—H Bond in the Benzene Ring of 2-Arylpyridines.
✍ Scribed by Naoto Chatani; Takeshi Uemura; Taku Asaumi; Yutaka Ie; Fumitoshi Kakiuchi; Shinji Murai
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 47 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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Rhodium-Catalyzed Reaction of N-(2-Pyridinyl)piperazines with CO and Ethylene. A Novel Carbonylation at a C-H Bond in the Piperazine Ring. -The electronic nature of substituents, both on the 4-nitrogen and in the pyridine ring, affects significantly the reactivity of the substrates in the novel tit