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ChemInform Abstract: Direct Carbonylation at a C—H Bond in the Benzene Ring of 2-Phenyloxazolines Catalyzed by Ru3(CO)12. Scope, Limitations, and Mechanistic Aspects.

✍ Scribed by Yutaka Ie; Naoto Chatani; Takashi Ogo; Daniel R. Marshall; Takahide Fukuyama; Fumitoshi Kakiuchi; Shinji Murai


Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Rhodium-Catalyzed Reaction of N-(2-Pyridinyl)piperazines with CO and Ethylene. A Novel Carbonylation at a C-H Bond in the Piperazine Ring. -The electronic nature of substituents, both on the 4-nitrogen and in the pyridine ring, affects significantly the reactivity of the substrates in the novel tit