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ChemInform Abstract: Rhodium-Catalyzed Reaction of N-(2-Pyridinyl)piperazines with CO and Ethylene. A Novel Carbonylation at a C—H Bond in the Piperazine Ring.

✍ Scribed by Y. ISHII; N. CHATANI; F. KAKIUCHI; S. MURAI

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Rhodium-Catalyzed Reaction of N-(2-Pyridinyl)piperazines with CO and Ethylene. A Novel Carbonylation at a C-H Bond in the Piperazine Ring.

-The electronic nature of substituents, both on the 4-nitrogen and in the pyridine ring, affects significantly the reactivity of the substrates in the novel title carbonylation, which involves dehydrogenation and carbonylation at a C-H bond. The pyridine ring has a dramatic effect on both reactivity and regioselectivity. -(ISHII, Y.; CHATANI, N.; KAKIUCHI, F.;

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