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Rhenium complexes from alkynes. X-Ray crystal structures of Re2(μ-2η1,-C4Ph4) (CO)7 and Re{C,O-CH C[Re(CO)4(NMe3)]C(OMe)O}(CO)4

✍ Scribed by Michael I. Bruce; Paul J. Low; Brian W. Skelton; Allan H. White


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
483 KB
Volume
464
Category
Article
ISSN
0022-328X

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Inhaltsu È bersicht. In THF-Lo È sung reagierte das in situ dargestellte Salz Li[Re 2 (l-H)(l-PCy 2 )(CO) 7 (ax-C(Ph)O)] (2) mit jeweils 1,5 Øquivalenten Monocarbonsa È ure RCOOH (R = H, Me, CF 3 , Ph, 3,4-(OMe) 2 C 6 H 3 ) bei 60 °C in 4 h beinahe quantitativ unter Freisetzung von Benzaldehyd (PhCH