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The study of isolobal displacement reactions. Synthesis and structures of the heterobimetallic μ-alkyne cluster complexes η-RC5H4(CO)2M(μ-R1C2R2)Co(CO)3 (MMo, W; RCH3C(O), CH3O2C)

✍ Scribed by Song Li-Cheng; Shen Jin-Yu; Hu Qing-Mei; Han Bing-Song; Wang Ru-Ji; Wang Hong-Gen


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
554 KB
Volume
219
Category
Article
ISSN
0020-1693

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📜 SIMILAR VOLUMES


Synthesis and Structure of the First η3-
✍ Lothar Weber; Gabriel Noveski; Ulrich Lassahn; Hans-Georg Stammler; Beate Neuman 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB 👁 1 views

## Abstract Reaction of [(η^5^‐C~5~H~5~)(CO)~2~M=P=C(SiMe~3~)~2~] [where M = Mo (2), W (5)] with the phosphaalkene __t__BuP=C(NMe~2~)~2~ (1a) afforded the η^3^‐1,2‐diphosphaallyl complexes [(η^5^‐C~5~H~5~)(CO)~2~M{η^3^‐__t__BuPPC(SiMe~3~)~2~}], [where M = Mo (3a); M = W (6)]. Similarly, 2 and CyP=C