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Synthesis and characterization of chiral SFeCoM(CO)8(RCOCp) (M = Mo, W; R = H, CH3, C2H5O) clusters and the crystal structure of SFeCoW(CO)8(CH3COCp)

✍ Scribed by He-Ping Wu; Yuan-Qi Yin; Qing-Chuan Yang


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
389 KB
Volume
245
Category
Article
ISSN
0020-1693

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The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit